lipid hydroperoxides glutathione (GSH) redox cycle in hydroperoxide metabolism. GSSG, Glutathione peroxidase - Wikipedia

Specifically, the leakage of electrons from mitochondrial ETC complexes gives rise to ROS, which can subsequently react with ferrous ions (Fe 2+ ) to generate OH radicals [89]

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Dysregulation of this equilibrium drives cardiac and vascular pathology through mechanisms such as mitochondrial dysfunction, altered substrate preference, and metabolic pathway reprogramming